SIM-RUC
Surface & Interface Modeling
for Emerging Nanomaterials and Devices

Retention of chirality in electron-induced reaction

Fang Cheng,ab Lydie Leung,b Chen-Guang Wang,bc Wei Ji,c and John C. Polanyi*b

DOI:10.1039/C6CC00849F    Publication Date: 05 Apr 2016


Abstract:

Two enantiomers were observed by Scanning Tunneling Microscopy (STM) when meta-iodopyridine was physisorbed on a 4.6 K Cu(110) surface. The chirality of the reagent was retained in the products of the electron-induced reaction. Dynamical calculations showed this to be a consequence of reaction occurring on one side of the mirror plane.


Keywords:


View: Chem. Commun.  52, 6115-6118 (2016)    

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