Surface & Interface Modeling
for Emerging Nanomaterials and Devices

Stacking tunable interlayer magnetism in bilayer CrI3

Peiheng Jiang1,†, Cong Wang2,†, Dachuan Chen1, Zhicheng Zhong1,*, Zhe Yuan3, Zhong-Yi Lu2 and Wei Ji2,*

1 Key Laboratory of Magnetic Materials and Devices & Zhejiang Province Key Laboratory of Magnetic Materials and Application Technology, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, P.R. China
2 Beijing Key Laboratory of Optoelectronic Functional Materials & Micro-Nano Devices, Department of Physics, Renmin University of China, Beijing 100872, P.R. China
3 The Center for Advanced Quantum Studies and Department of Physics, Beijing Normal University, Beijing 100875, China
Emails: (W.J.) and (Z.Z.)

DOI:10.1103/PhysRevB.99.144401    Publication Date:  1 April 2019


Diverse interlayer tunability of physical properties of two-dimensional layers mostly lies in the covalent-like quasi-bonding that is significant in electronic structures but is rather weak for energetics. Such characteristics result in various stacking orders that are energetically comparable but may significantly differ in terms of electronic structures, e.g. magnetism. Inspired by several recent experiments showing interlayer anti-ferromagnetically coupled CrI3 bilayers, we carried out first-principles calculations for CrI3 bilayers. We found that the anti-ferromagnetic coupling results from a new stacking order with the C2/m space group symmetry, rather than the graphene-like one stacking order with the space group symmetry as previously believed. Moreover, we demonstrated the intra- and inter-layer couplings in CrI3 bilayer are governed by two different mechanisms, namely ferromagnetic super-exchange and direct-exchange interactions, which are largely decoupled because of their significant difference in strength at the strong- and weak-interaction limits. This allows the much weaker interlayer magnetic coupling to be more feasibly tuned by stacking orders solely. Given the fact that interlayer magnetic properties can be altered by changing crystal structure with different stacking orders, our work opens a new paradigm for tuning interlayer magnetic properties with the freedom of stacking order in two dimensional layered materials.


View: Phys. Rev. B  99, 144401 (2019)     arXiv:1806.09274    

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